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14. Oprah Winfrey
Not only is Oprah –– well, Oprah –– but she's also been devoted to charity work and educational causes for years; most notably, charter schools and programs that support African-American students.

Oprah's Angel Network, for example, gave away 150 $25,000 scholarships, on its inception in 1998. But education wasn't the only cause benefited by the network, as Oprah personally covered its administrative costs, and in later years donated at least $11 million to disasters like hurricanes Katrina and Rita.

She's also made significant contributions for disaster relief via foundations like Habitat for Humanity, among others. And that's only the tip of the iceberg!