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21. Reese Witherspoon & Jim Toth
Toth is a Hollywood agent whose clients include Scarlett Johansson and Robert Downey Jr.

Witherspoon met him at a bar after her 2009 breakup with Jake Gyllenhaal, and he actually came to her rescue after his drunken friend (coming down from a bad breakup himself) started to aggressively hit on her at the bar. Swooping in and pushing the friend along, that was his first encounter with his future wife. The duo married in 2011.