5. Blair and Chuck from 'Gossip Girl'
You know you still love this viciously wonderful couple. They captured elegance and arrogance throughout the course of their whole relationship. If you want to look like you came straight from the Upper East Side, take notes. 

Chuck: If you can get your hands on a tux, go with it. If not, try a plain black suit and slick your hair in a chic coif, Bass-style. 

Blair: Anything preppy or fancy will do, but if you're looking to channel a familiar look, try a pleated skirt and blouse with a jeweled hairband. Curl your hair, and make sure to end your sentences with "xoxo, B".