9. Olivia and Fitz from 'Scandal'
It's a love affair of presidential proportions. If you're dying to live out your own scandal, try dressing up like the desirable Olivia Pope and Fitzgerald Grant. 

Olivia: Well tailored blazer and skirt, paired with pumps and a glass of red wine. 

Fitz: Suit of any color, just don't forget the American flag pin.