(Source: Summit Entertainment)
Prev 12 of 56 Next
12. Brad Pitt and Angelina Jolie in 'Mr. & Mrs. Smith'
Under some controversial circumstances, Mr. and Mrs. Pitt united on the set of Mr. and Mrs. Smith. The film released in 2005, Angelina Jolie gave birth to their first child in 2006, the couple announced their engagement in 2012 and finally married in 2014. They have six children together.

After two years of marriage and more than a decade together, the couple cited irreconcilable differences, and filed for divorce in late 2016.