(May 10, 2004 - Source: Peter Kramer/Getty Images Entertainment) more pics like this »
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21. 2005: Brad Pitt & Jennifer Aniston
Would you look at those baby faces? It's hard to believe this couple split over 10 years ago! This power couple's breakup after five years shocked the world, but not as much as the cheating allegations regarding Pitt and Angelina Jolie.