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37. Naomi Watts and Heath Ledger
These two were one of Hollywood's most attractive couples for the two years they dated, from 2002-2004. He passed away four years later and Watts talked about their relationship in an interview in 2011: “We had a beautiful relationship, only a couple of years, but he was a man who was completely full of joy, and there was a lot of laughing and affection. He was really a very special soul and made a great impact on my life. And a great actor, but I know there was so much more to come. And it’s such a tragedy for his little daughter.”