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10. Ellen Pompeo & Chris Ivery
The actress first met her music producer husband in the produce aisle of an LA grocery store, like they were the two starring leads in a 1990's rom-com. They met two years before Grey’s Anatomy premiered, so Pompeo wasn't the household name yet that she is now. It took them six months to start dating after their first meeting, though - Ivery said that they were just friends until, “one night she just looked different to me.” The pair was married in 2007.