August 31, 2006 - Evan Agostini/Getty Images Entertainment more pics like this »
7. Jennifer Lopez 2006
Also looking quite the diva at the 2006 show was Jennifer Lopez, who donned a high-neck silver mini dress with blouson sleeves and a matching head scarf. The singer added a dose of edge with a pair of taupe over-the-knee boots and sealed off her ensemble with a metallic silver clutch.

For her beauty look, JLo went edgy as well with a super smoky eye. Sparkling studs and some silver bangles rounded out her ensemble. This was a chic '60s-inspired look from the star. Love it!