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14. Nina Dobrev in Donna Karan, 2012
Still at the 2012 event, Nina Dobrev made a dazzling entrance in a Donna Karan Atelier gown that featured an asymmetrical neckline, an open back, and gold sequin embellishments. The best part? An ultra-long train that definitely had a life of its own! The actress finished off her look with a regal chignon and H. Stern jewels.

Here's an interesting piece of trivia about this dress: she had to be sewn into it before the event, cut out of it so she could go to the toilet, and then sewn back in afterwards. Wow, the things people do for fashion!