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32. 2016: Brad Pitt & Angelina Jolie
After meeting on the set of Mr. and Mrs. Smith, the two A-listers began publicly dating after Pitt's divorce from Jennifer Aniston. After many yaers and children together, Jolie filed for divorce in 2016, citing irreconcilable differences. At the time, rumors circulated about Pitt having a drinking problem and a possible incident of child abuse, though he was cleared of those charges.